{"id":5089,"date":"2019-06-22T01:53:15","date_gmt":"2019-06-22T05:53:15","guid":{"rendered":"http:\/\/maxtorqueperformance.com\/?p=5089"},"modified":"2019-06-22T02:09:13","modified_gmt":"2019-06-22T06:09:13","slug":"misunderstood-causes-of-detonation-in-high-performance-applications","status":"publish","type":"post","link":"https:\/\/maxtorqueperformance.com\/staging\/index.php\/2019\/06\/22\/misunderstood-causes-of-detonation-in-high-performance-applications\/","title":{"rendered":"Misunderstood Causes of Detonation in High Performance Applications"},"content":{"rendered":"<div>\n<header class=\"entry-header clearfix\" style=\"box-sizing: border-box;        color: rgb(51, 51, 51); display: block; font-family:        Arial,sans-serif; font-size: 14px; font-style: normal;        font-variant: normal; font-weight: 400; letter-spacing: normal;        margin-bottom: 30px; orphans: 2; text-align: left;        text-decoration: none; text-indent: 0px; text-transform: none;        -webkit-text-stroke-width: 0px; white-space: normal; word-spacing:        0px;\">\n<div class=\"entry-meta\" style=\"box-sizing: border-box; font-size:          14px;\">\n<div class=\"avatar\" style=\"box-sizing: border-box; float: left;            height: 50px; margin-right: 20px; width: 50px;\">            <a class=\"author crop crop-image_290_290\"              href=\"https:\/\/www.enginelabs.com\/author\/jenniferszabo\/\"              style=\"background-color: transparent;              border-bottom-left-radius: 50%; border-bottom-right-radius:              50%; border-top-left-radius: 50%; border-top-right-radius:              50%; box-sizing: border-box; color: rgb(51, 122, 183);              display: block; height: 0px; overflow: hidden;              padding-bottom: 100%; padding-left: 0px; padding-right: 0px;              padding-top: 0px; position: relative; text-decoration:              none;\">              <img decoding=\"async\" style=\"border-bottom-color: currentColor;                border-bottom-style: none; border-bottom-width: 0px;                border-image-outset: 0; border-image-repeat: stretch;                border-image-slice: 100%; border-image-source: none;                border-image-width: 1; border-left-color: currentColor;                border-left-style: none; border-left-width: 0px;                border-right-color: currentColor; border-right-style:                none; border-right-width: 0px; border-top-color:                currentColor; border-top-style: none; border-top-width:                0px; box-sizing: border-box; height: 50px; object-fit:                cover; vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.enginelabs.com\/wp-content\/userphoto\/jenniferszabo.thumbnail.jpg\"                width=\"80\"> <\/a>          <\/div>\n<p>          <span class=\"byline\" style=\"box-sizing: border-box; color:            rgb(165, 165, 165); display: inline-block; margin-top: 15px;\">            By            <span class=\"author vcard\" style=\"box-sizing: border-box;\">              <a class=\"url fn n\"                href=\"https:\/\/www.enginelabs.com\/author\/jenniferszabo\/\"                style=\"background-color: transparent; box-sizing:                border-box; color: rgb(92, 92, 92); font-weight: 700;                text-decoration: none; text-transform: uppercase;\">Jennifer                Szabo<\/a>            <\/span>          <\/span>          <span class=\"posted-on\" style=\"box-sizing: border-box; color:            rgb(165, 165, 165); text-transform: uppercase;\">June 20, 2019<\/span>        <\/div>\n<\/header>\n<p>      <span style=\"display: inline !important; float: none;        background-color: rgb(255, 255, 255); color: rgb(51, 51, 51);        font-family: Arial,sans-serif; font-size: 14px; font-style:        normal; font-variant: normal; font-weight: 400; letter-spacing:        normal; orphans: 2; text-align: left; text-decoration: none;        text-indent: 0px; text-transform: none; -webkit-text-stroke-width:        0px; white-space: normal; word-spacing: 0px;\">      <\/span>      <\/p>\n<div class=\"entry-content\" style=\"box-sizing: border-box; color:        rgb(71, 71, 71); font-family: Arial,sans-serif; font-size: 16px;        font-style: normal; font-variant: normal; font-weight: 400;        letter-spacing: normal; line-height: 24px; orphans: 2; text-align:        left; text-decoration: none; text-indent: 0px; text-transform:        none; -webkit-text-stroke-width: 0px; white-space: normal;        word-spacing: 0px;\">\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 30px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">In the engine tuning          world, detonation is defined as one of the following: combustion          that causes engine damage; combustion that causes banging or          pinging noises; or combustion that causes power loss, bucking,          or kicking. Detonation is not controlled and often unwanted. It          occurs when fuel in the cylinder auto-ignites outside the          intended flame front of the spark ignition.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Detonation does not          always cause damage. At lower engine loadings during part          throttle or low RPM, detonation may be warranted. For example,          during the late \u201970s and \u201980s, pinging during normal operation          was common with carbureted engines. Certain intake manifold          design compromises combined with smog equipment caused lean fuel          mixtures that burned outside of the controlled flame front from          the spark plug.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Minor detonation          sometimes occurs that is not heard through mufflers at low load          or even with loud open exhaust. Major detonation causes a more          severe noise during engine loading where the throttle is open          and the engine is twisting hard against a heavy load.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">        <\/p>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Detonation            and Preignition<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Preignition is          auto-ignition of the air\/fuel mixture before the spark plug          fires. The auto-ignition occurs at a location in the cylinder          outside of the controlled flame front from spark ignition.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Similarly, detonation is          auto-ignition of fuel, usually after the spark plug fires. Like          preignition, detonation occurs outside of a controlled flame          front from the spark plug. The term detonation is often used by          racers as both preignition (before the spark), as well as          uncontrolled burning after the spark. The same convention is          used in this article.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1087236\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_20-57-02_106369.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-249212 size-large\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_20-57-02_106369-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">This illustration is from <em              style=\"box-sizing: border-box;\">5000 Horsepower on Methanol<\/em>            (<a              href=\"https:\/\/racecarbook.com\/shop\/5000-horse-power-on-methanol\/\"              style=\"background-color: transparent; box-sizing:              border-box; color: rgb(255, 93, 31); text-decoration: none;\">Bob              Szabo, Szabo Publishing, 2006<\/a>) showing auto-ignition            temperatures for various racing fuels.<\/p>\n<\/p><\/div>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_3 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\" data-displayed=\"cluster_3\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_3\">        <\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Both preignition and          detonation are from auto-ignition of fuel. They share          characteristics \u2014 like a very high burn speed \u2014 which are          comparable to explosive flame speeds. These include firearms          muzzle velocities or explosives combustion velocities \u2014          typically well over 1,000 feet per second. The high velocity          causes noise due to pressure fronts that collide within the          cylinder.<\/p>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Detonation            and RPM<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Detonation can be masked          at higher RPM by high frequency noise, like that of an exhaust          valve opening. It can be such a brief occurrence that it doesn\u2019t          cause damage before the exhaust valve opens, relieving the          cylinder pressure and ending the detonation.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">At lower engine speeds          the time between detonation and opening of the exhaust valve is          a longer interval, so detonation is more noticeable. As the RPM          increases, it may sound like the detonation goes away because of          shorter intervals between detonation and opening of the exhaust          valve.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Racing engines in the          \u201930s and \u201940s ran on lower octane gasoline, as higher octane          gasoline was not yet developed. The lower octane fuels were          susceptible to detonation as racers raised engine compression          ratio for more power. Detonation was especially detectable at          low engine speeds. To combat the low-speed detonation, those          early racing engines were revved continuously at higher engine          speeds to inhibit the effects of detonation.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">If the engine was lugged          by mistake, detonation could cause poor performance and possible          engine damage. As a result, drivers coming into the pits for          service would free-rev their engines continuously. Slipping the          clutch to launch from the pits became an art form for many          successful racing drivers. When starting in the pits, there was          a great risk of engine stalling from a combination of inadequate          clutch slipping, low engine torque at low-RPM, and detonation at          low-RPM.<\/p>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_1 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\"          data-displayed=\"cluster_3;cluster_1\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_1\">        <\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">The best performance for          modern day gasoline-fueled engines is achieved with a racing          gasoline blend with an octane rating just high enough to avoid          detonation. A gasoline blend with a higher octane rating does          not usually increase performance by itself. Instead, the slower          burn rate of high octane gasoline will often actually reduce an          engine\u2019s performance without other changes made to take          advantage of the higher octane.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Gasoline\u2019s octane need          is characteristic of a specific RPM operating range. If that          range is changed, a racing gasoline with a different octane may          be needed. For example, if the engine spends more time under          load at a lower engine speed, the engine may encounter          detonation, whereas it would not detonate at the same load          higher in the RPM range. A racing gasoline with a higher octane          may be needed to combat the potential for detonation operating          in the lower RPM range.<\/p>\n<section class=\"group-caption group-caption-rendered\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: rgb(255, 255, 255);          background-image: none; background-origin: padding-box;          background-position-x: 0%; background-position-y: 0%;          background-repeat: repeat; background-size: auto;          border-bottom-color: currentColor; border-bottom-style: none;          border-bottom-width: 0px; border-image-outset: 0;          border-image-repeat: stretch; border-image-slice: 100%;          border-image-source: none; border-image-width: 1;          border-left-color: currentColor; border-left-style: none;          border-left-width: 0px; border-right-color: currentColor;          border-right-style: none; border-right-width: 0px;          border-top-color: currentColor; border-top-style: none;          border-top-width: 0px; box-sizing: border-box; display: block;          margin-bottom: 10px; margin-left: 0px; margin-right: 0px;          margin-top: 10px; max-width: none; padding-bottom: 0px;          padding-left: 0px; padding-right: 0px; padding-top: 0px;\">\n<ul class=\"list-attachments thumbnails row-1 clearfix\"            style=\"box-sizing: border-box; display: block; line-height:            24px; margin-bottom: 5px; margin-left: 0px; margin-right: 0px;            margin-top: 0px; padding-bottom: 0px; padding-left: 0px;            padding-right: 0px; padding-top: 0px;\">\n<li class=\"thumbnail col-2\" style=\"background-color: rgb(255,              255, 255); border-bottom-color: currentColor;              border-bottom-left-radius: 4px; border-bottom-right-radius:              4px; border-bottom-style: none; border-bottom-width: medium;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: medium;              border-right-color: currentColor; border-right-style: none;              border-right-width: medium; border-top-color: currentColor;              border-top-left-radius: 4px; border-top-right-radius: 4px;              border-top-style: none; border-top-width: medium;              box-sizing: border-box; clear: both; display: block; float:              left; line-height: 1.4285; margin-bottom: 0px;              padding-bottom: 0px; padding-left: 0px; padding-right: 0px;              padding-top: 0px; transition-delay: 0s; transition-duration:              0.2s; transition-property: border;              transition-timing-function: ease-in-out; width: 50%;\"><a                class=\"group-caption-image-box\"  href=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-08_910330.jpg\"                rel=\"shadowbox[sbpost-249002];player=img;\"                style=\"background-color: transparent; border-bottom-color:                currentColor; border-bottom-style: none;                border-bottom-width: 0px; border-image-outset: 0;                border-image-repeat: stretch; border-image-slice: 100%;                border-image-source: none; border-image-width: 1;                border-left-color: currentColor; border-left-style: none;                border-left-width: 0px; border-right-color: currentColor;                border-right-style: none; border-right-width: 0px;                border-top-color: currentColor; border-top-style: none;                border-top-width: 0px; box-sizing: border-box; color:                rgb(255, 93, 31); display: block; padding-right: 5px;                text-decoration: none;\"  data-image-mobile=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-08_910330.jpg\"><img decoding=\"async\"                  style=\"border-bottom-color: currentColor;                  border-bottom-style: none; border-bottom-width: 0px;                  border-image-outset: 0; border-image-repeat: stretch;                  border-image-slice: 100%; border-image-source: none;                  border-image-width: 1; border-left-color: currentColor;                  border-left-style: none; border-left-width: 0px;                  border-right-color: currentColor; border-right-style:                  none; border-right-width: 0px; border-top-color:                  currentColor; border-top-style: none; border-top-width:                  0px; box-sizing: border-box; display: block; height:                  auto; margin-bottom: 0px; margin-left: 0px;                  margin-right: 0px; margin-top: 0px; max-width: 100%;                  vertical-align: bottom; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-08_910330.jpg\"                  data-lazy-loaded=\"true\"><\/a><\/li>\n<li class=\"thumbnail col-2\" style=\"background-color: rgb(255,              255, 255); border-bottom-color: currentColor;              border-bottom-left-radius: 4px; border-bottom-right-radius:              4px; border-bottom-style: none; border-bottom-width: medium;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: medium;              border-right-color: currentColor; border-right-style: none;              border-right-width: medium; border-top-color: currentColor;              border-top-left-radius: 4px; border-top-right-radius: 4px;              border-top-style: none; border-top-width: medium;              box-sizing: border-box; display: block; float: left;              line-height: 1.4285; margin-bottom: 0px; padding-bottom:              0px; padding-left: 0px; padding-right: 0px; padding-top:              0px; transition-delay: 0s; transition-duration: 0.2s;              transition-property: border; transition-timing-function:              ease-in-out; width: 50%;\"><a class=\"group-caption-image-box\"  href=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-12_618666.jpg\"                rel=\"shadowbox[sbpost-249002];player=img;\"                style=\"background-color: transparent; border-bottom-color:                currentColor; border-bottom-style: none;                border-bottom-width: 0px; border-image-outset: 0;                border-image-repeat: stretch; border-image-slice: 100%;                border-image-source: none; border-image-width: 1;                border-left-color: currentColor; border-left-style: none;                border-left-width: 0px; border-right-color: currentColor;                border-right-style: none; border-right-width: 0px;                border-top-color: currentColor; border-top-style: none;                border-top-width: 0px; box-sizing: border-box; color:                rgb(255, 93, 31); display: block; padding-right: 5px;                text-decoration: none;\"  data-image-mobile=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-12_618666.jpg\"><img decoding=\"async\"                  style=\"border-bottom-color: currentColor;                  border-bottom-style: none; border-bottom-width: 0px;                  border-image-outset: 0; border-image-repeat: stretch;                  border-image-slice: 100%; border-image-source: none;                  border-image-width: 1; border-left-color: currentColor;                  border-left-style: none; border-left-width: 0px;                  border-right-color: currentColor; border-right-style:                  none; border-right-width: 0px; border-top-color:                  currentColor; border-top-style: none; border-top-width:                  0px; box-sizing: border-box; display: block; height:                  auto; margin-bottom: 0px; margin-left: 0px;                  margin-right: 0px; margin-top: 0px; max-width: 100%;                  vertical-align: bottom; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/04\/misunderstood-causes-of-detonation-in-high-performance-applications-2019-05-08_21-06-12_618666.jpg\"                  data-lazy-loaded=\"true\"><\/a><\/li>\n<\/ul>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 5px; margin-top: 20px; padding-bottom: 10px;            padding-left: 15px; padding-right: 10px; padding-top: 10px;            text-align: left;\">Illustrations from <em style=\"box-sizing:              border-box;\">5000 Horsepower on Methanol<\/em> showing            cylinder pressure vs. crankshaft angle for good combustion on            left and detonation on right.<\/p>\n<\/section>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Dissociation            From Combustion<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Fuels dissociate, or          break down, into different intermediate chemicals during          compression, heating, and combustion. These intermediate          chemicals can alter the auto-ignition temperature of the mixture          from that of the original fuel alone. Many times, the wrong          tune-up call is made because of detonation, assuming data based          on just the properties of the primary fuel, when auto-ignition          temperature changes from dissociation should have been taken          into account.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">In blown alcohol drag          racing, competitors with higher static compression usually have          to run a richer mixture than those with lower static compression          to inhibit detonation. However, there is a point at which the          need for additional enrichment tapers off. One competitor          reported that beyond a certain point in compression increases,          further enrichment was not needed, while the engine made more          power with more compression. He continued to raise compression          further and achieved national record-running performance. At a          certain point, the extra-high compression was actually          preventing the formation of detonation-sensitive dissociates.<\/p>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_2 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\"          data-displayed=\"cluster_3;cluster_1;cluster_2\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_2\">        <\/div>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><b            style=\"box-sizing: border-box; font-weight: 700;\">Dissociate<\/b><strong            style=\"box-sizing: border-box; font-weight: 700;\">\u00a0Causes of            Detonation<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">With different racing          fuels, some of the previously described dissociate formations          can be more prone to detonation than others. The tune-up can          affect the compression and heating which will affect what          dissociates are formed, even with the same fuel. These          dissociates then affect the detonation sensitivity.          Additionally, air density changes affect the tune-up which, once          again, affects dissociation in a vicious cycle.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">For example, changing          the closing point of the intake valve in a spark ignition racing          engine will change the effective dynamic compression. Changing          the compression changes the adiabatic heating and pressure from          compression. Sensitivity towards or away from detonation can be          triggered by something as simple as a camshaft change or even          just retarding or advancing camshaft timing.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072648\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-26_313637.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-249207\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-26_313637-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">This illustration from <em              style=\"box-sizing: border-box;\">5000 HP on Methanol<\/em>            shows the relationship between compression ratio and air\/fuel            ratio for detonation-free operation for methanol racing fuel.            Data points, (a) through (e) were determined from various            racing engines. This curve also depends on a proper level of            enrichment to retard auto-ignition that is further described            in the reference.<\/p>\n<\/p><\/div>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Pressure            Changes Causing\u00a0<\/strong><b style=\"box-sizing: border-box;            font-weight: 700;\">Ignition<\/b><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Pressure changes the          auto-ignition temperature of both the fuel and fuel dissociates,          which can initiate detonation. An auto-ignition temperature of a          fuel dissociate may be lower than the auto-ignition temperature          of the fuel before it breaks down, which can be confusing, when          looking at the data for the fuel alone.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">During compression, say          a mixture of air and dissociated fuel is below the auto-ignition          temperature. The pressure wave generated in the cylinder can          inhibit this mixture from igniting. However, as the pressure          wave goes through the cylinder, it can trigger a change in the          auto-ignition temperature of the mixture. Auto-ignition can          follow as the pressure wave passes due to the accompanying drop          in auto-ignition temperature, strictly from the chemical          sensitivity change. Additionally, changes in the cylinder head          from piston squish or unshrouding an intake valve can change the          pressure wave formation and affect the combination\u2019s overall          detonation sensitivity.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072649\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-33_138851.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-249208\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-33_138851-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">The O-ring indent on this used copper head            gasket around the cylinder opening shows the start of            burn-through in the tight O-ring mating surface just before            detonation from a nitromethane methanol fuel mixture.            Enrichment to this cylinder &amp; new head gasket avoided a            reoccurrence.\u00a0Photo Credit:\u00a0<em style=\"box-sizing:              border-box;\">Blown Nitro Racing on a Budget<\/em> (<a              href=\"https:\/\/racecarbook.com\/shop\/blown-nitro-racing-on-a-budget\/\"              style=\"background-color: transparent; box-sizing:              border-box; color: rgb(255, 93, 31); text-decoration: none;\">Bob              Szabo, Szabo Publishing 2013<\/a>).<\/p>\n<\/p><\/div>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_2 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\" data-displayed=\"cluster_2\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_2\">        <\/div>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Dissociation            With Different Fuels<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Gasoline<\/strong><\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">According to writings by          the late Harry Ricardo (<a href=\"https:\/\/ricardo.com\/\"            target=\"_blank\" style=\"background-color: transparent;            box-sizing: border-box; color: rgb(255, 93, 31);            text-decoration: none;\" rel=\"noopener noreferrer\">The High-Speed Internal-Combustion            Engine, 3rd Edition, Blackie &amp; Son Limited, 1950<\/a>), who          was a combustion engineering expert, unstable peroxides are          formed as intermediate dissociates during gasoline combustion,          which happen to be very prone to detonation. Tetra-ethyl lead is          a reactive metallic addition that suppresses detonation from          these unstable peroxides. In addition, various gasoline fuel          constituents used in common blends have different dissociation          properties to help combat the formations of the unstable          peroxides. Examples of these constituents used are pentane,          hexane, and toluene.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Fuel blending in modern          gasolines is done to achieve detonation resistance, among other          characteristics. In many racing gasoline brands, several are          also blended with tetra-ethyl lead for the same purpose. Other          characteristics such as chemical stability, ease of vaporization          so that the engine can be started, and manufacturing cost, often          limit blend additives and ratios. Those constraints can          compromise the detonation resistance capability of some gasoline          brands over others under given circumstances. The ideal result          is a best-fit mixture or blend to fulfill the particular racing          requirement, and why so many different racing gasoline          variations exist.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Gasoline blends sold at          the pump most often have seasonal changes in blend ratios and          fuel content. Winter gasoline is blended for ease of starting,          while summer gasoline blends are designed for vapor-lock          avoidance. Different seasonal blends will change the          dissociation and detonation characteristics, and needs to be          accounted for in a performance application. Pump gasoline          purchased in one season may encounter detonation issues if it is          run in another season, due to the variance in blend.<\/p>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_3 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\"          data-displayed=\"cluster_2;cluster_3\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_3\">        <\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Ethanol            Gasoline Blends (E85)<\/strong><\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">E85 is predominantly          (85-percent) ethanol with a small amount (15-percent) of          gasoline added. The ethanol content\u2019s high effective octane          rating suppresses detonation in high-compression-ratio racing          engine if the air\/fuel ratio is rich. That would be a lambda of          less than one in the EFI computer world. A rich alcohol fuel          mixture also cools the cylinder away from auto-ignition          temperatures. These rich air\/fuel ratios can be run with a          predominant alcohol fuel since alcohol does not foul out a spark          plug like other fuels can. However, excessive richness reduces          power output, so tuning the air\/fuel ratio is vital. On the          other end of the specturm, excessively rich mixtures can cool          the intake too much, suppressing vaporization and inducing          detonation from a vapor lean condition. This is the result of          excess fuel condensation from cooling.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Methanol<\/strong><\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Methanol as well as          ethanol will dissociate into hydrogen and carbon monoxide during          compression heating. Methanol and ethanol will also partially          dissociate into hydrogen and carbon monoxide during boost in an          engine with large enough pressures from forced induction, prior          to, and in addition to piston compression. However, compression          pressure retards the amount of dissociation that occurs.          Therefore heat causes dissociation to go in one direction, and          pressure from compression (or boost) causes dissociation to go          in another. Combustion is then a combination of hydrogen, carbon          monoxide, and any remaining methanol vapor that has not          dissociated.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072645\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-06_070301.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-large wp-image-249204\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-06_070301-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">A Funnycar Dragster launches for 300 mph            drag race runs at Norwalk Raceway Park, Ohio during an IHRA            national event with detonation fighting tune-ups from            high-percentage nitromethane methanol fuel mixtures<\/p>\n<\/p><\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Differences in          compression, engine temperature, camshaft timing, and boost in          forced induction engines all affect the amount of dissociation          that occurs. The amount of dissociation then affects the          combustion characteristics of the charge. For example: hydrogen          has very low ignition temperature and is more prone to          backfiring into the intake, as it doesn\u2019t necessarily need a          traditional ignition source. That is often mistaken as          detonation when, in fact, it is excess hydrogen dissociation          that is reacting.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">A tune-up or air density          change can change the hydrogen dissociation and make or avoid          engine backfiring. When backfiring from hydrogen dissociation          occurs, subsequent engine disassembly often does not reveal any          engine damage. The variation in auto-ignition temperatures of          methanol is due to different amounts of dissociation from the          tune-up and air density changes.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Methanol has oxygen in          the fuel while traditional gasoline does not. As such, methanol          can detonate with less air in the mix than gasoline. An air\/fuel          weight-ratio of 8-to-1 would be overly rich for gasoline and not          detonate but could detonate with methanol fuel. That threshold          changes with oxygen variations in the air from air density          changes.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072650\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-39_441190.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-249209\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-39_441190-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">Data as reported in <em style=\"box-sizing:              border-box;\">5000 HP on Methanol<\/em> from Germane and            Lovell indicate a relationship between the amount of carbon in            a fuel molecule and auto-ignition temperature. (Germane, Geoff            J., Brigham Young University, <a              href=\"https:\/\/www.sae.org\/publications\/technical-papers\/content\/852129\/\"              style=\"background-color: transparent; box-sizing:              border-box; color: rgb(255, 93, 31); text-decoration: none;\">A              Technical Review of Automotive Racing Fuels<\/a>, SAE 1985,            Publication #852129)(Lovell, W. G., Knocking Characteristics            of Hydrocarbons, Industrial and Engineering Chemistry, Vol.            40, pp. 2388-2438, December, 1948)<\/p>\n<\/p><\/div>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_1 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\"          data-displayed=\"cluster_2;cluster_3;cluster_1\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_1\">        <\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Nitromethane<\/strong><\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Nitromethane dissociates          in different phases. For a brief moment, some of these phases          are sequential, and some are even simultaneous during the          ignition and combustion process. However, many phases of          nitromethane dissociation occur simply from compression heating          and combustion.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">The first phase is          endothermic. It absorbs heat and acts like it is hard to ignite.          This is why a magneto ignition with a long spark dwell time is          more effective with nitromethane fuel mixtures to get past the          first dissociation phase of combustion. The second and remaining          dissociation phases of nitromethane combustion can be          exothermic, that is, burning and giving off heat (<a            href=\"https:\/\/www.chemsupply.com.au\/documents\/NI0370_AU.pdf\"            target=\"_blank\" style=\"background-color: transparent;            box-sizing: border-box; color: rgb(255, 93, 31);            text-decoration: none;\" rel=\"noopener noreferrer\">Chem-Supply Material Safety Data            Sheet, nitromethane<\/a>, 1CHOP, December, 2000).<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Multiple dissociation          phases occur during combustion with different intermediate          compounds and with different auto-ignition (detonation)          characteristics. Different mixtures of nitromethane and methanol          add further complexity to detonation sensitivity changes since          methanol has its own set of dissociates and behaviors. As a          result, the tuning directions can be troublesome and          inconsistent from run to run.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Some nitro tune-ups may          be more prone to detonation when leaning the mixture (higher          air\/fuel ratio). Some nitro tune-ups may be more prone to          detonation with enrichment of the mixture (lower air\/fuel          ratio). The best tune-up routine is to make as few changes as          possible to engine compression, boost, fuel mixture, fuel          temperature, and others to dial-in engine power for the          performance envelope. Making multiple changes from run to run          makes it almost impossible to get control over the tune-up,          because of that wandering auto-ignition temperature          characteristic. Major engine failures can occur as a result.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072651\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-47_547346.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-249210\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-47_547346-960x649.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"649\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">Recent photo of 300 mph Nitro Funnycar drag            racecars staged for startup at an IHRA National Event drag            race with detonation-sensitive tune-ups from 90-percent            nitromethane mixtures.<\/p>\n<\/p><\/div>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_2 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\" data-displayed=\"cluster_2\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_2\">        <\/div>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Air\/Fuel            Ratio Changes<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Changes in air\/fuel          ratio will also change the auto-ignition sensitivity          characteristics. This change is complex depending on the amount          of enrichment. Enrichment up to a point tends to decrease the          auto-ignition sensitivity. Enrichment in methanol or ethanol can          cool the cylinder temperature to where the engine will not          detonate. Excess enrichment beyond a certain air\/fuel ratio with          those fuels can increase the auto-ignition sensitivity however.          By causing excessive cooling and fuel condensation out of the          inlet air charge, a vapor-lean condition is created and          auto-ignition can occur. It can also slow down the flame speed,          extending the combustion event into the exhaust stroke. That can          lead to a backfire in the intake when the intake valve opens.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">In the other direction,          less enrichment beyond a certain optimum air\/fuel ratio tends to          increase the auto-ignition sensitivity. With methanol or          ethanol, less enrichment will not cool the cylinder temperature          enough, raising temperature enough to where the engine may then          detonate, especially if high compression ratios are used.<\/p>\n<div class=\"wp-caption alignnone\" id=\"attachment_1072652\"          style=\"background-attachment: scroll; background-clip:          border-box; background-color: transparent; background-image:          none; background-origin: padding-box; background-position-x:          0px; background-position-y: 0px; background-repeat: repeat;          background-size: auto; border-bottom-color: currentColor;          border-bottom-style: none; border-bottom-width: 0px;          border-image-outset: 0; border-image-repeat: stretch;          border-image-slice: 100%; border-image-source: none;          border-image-width: 1; border-left-color: currentColor;          border-left-style: none; border-left-width: 0px;          border-right-color: currentColor; border-right-style: none;          border-right-width: 0px; border-top-color: currentColor;          border-top-style: none; border-top-width: 0px; box-sizing:          border-box; max-width: 930px; width: 970px;\"><a  href=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-54_402296.jpg\"            rel=\"shadowbox[sbpost-249002];player=img;\"            style=\"background-color: transparent; box-sizing: border-box;            color: rgb(255, 93, 31); display: block; text-decoration:            none;\"><img loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-249211\"              style=\"border-bottom-color: currentColor;              border-bottom-style: none; border-bottom-width: 0px;              border-image-outset: 0; border-image-repeat: stretch;              border-image-slice: 100%; border-image-source: none;              border-image-width: 1; border-left-color: currentColor;              border-left-style: none; border-left-width: 0px;              border-right-color: currentColor; border-right-style: none;              border-right-width: 0px; border-top-color: currentColor;              border-top-style: none; border-top-width: 0px; box-sizing:              border-box; display: inline; height: auto; max-width: 100%;              vertical-align: middle; width: 100%;\" alt=\"\"  src=\"https:\/\/www.speednik.com\/files\/2019\/03\/hidden-causes-of-detonation-2019-03-14_05-17-54_402296-960x640.jpg\"              data-lazy-loaded=\"true\" width=\"960\" height=\"640\"><\/a>          <\/p>\n<p class=\"wp-caption-text\" style=\"background-attachment: scroll;            background-clip: border-box; background-color: transparent;            background-image: none; background-origin: padding-box;            background-position-x: 0px; background-position-y: 0px;            background-repeat: repeat; background-size: auto;            border-left-color: rgb(255, 93, 31); border-left-style: solid;            border-left-width: 4px; box-sizing: border-box; color:            rgb(106, 106, 106); font-size: 16px; font-weight: 700;            line-height: 24px; margin-bottom: 15px; margin-left: 0px;            margin-right: 0px; margin-top: 20px; padding-left: 15px;            text-align: left;\">A unique race tuning trick is to run the            engine up to the limit of detonation then disassemble the            engine and measure the thickness of upper rod bearings. The            bearing on the left measured no thinning after a run. The            bearing on right is from the same cylinder after another run            with some detonation-induced thinning. Some engine            builder\/tuners use bearing thinning as an indicator of an            amount of detonation. Some early nitro drag racing engine            builder\/tuners mastered this method of a certain amount of rod            bearing thinning as an indicator of a good tune-up.<\/p>\n<\/p><\/div>\n<div class=\"ad responsive-ads clearfix apply-responsive-ads          clearfix with_sidebar select-cluster_3 processed\"          style=\"box-sizing: border-box; margin-bottom: 50px; margin-left:          -30px; margin-top: 50px; max-width: none; padding-left: 0px;          padding-right: 0px; width: 990px;\"          data-displayed=\"cluster_2;cluster_3\"          data-group-reponsive=\"desktop\" data-banner-count=\"\"          data-select-cluster=\"cluster_3\">        <\/div>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">Excessive reduction of          enrichment may reduce power since there is less fuel to burn.          Continued reduction of enrichment beyond a certain point may not          detonate since the extreme lean condition results in a shortage          of fuel to burn, and flame speed slows down. Somewhere in that          lean direction, flame speed can be slowed, continuing past the          exhaust stroke. That can then, like excessively rich conditions,          cause a backfire in the intake.<\/p>\n<h4 style=\"box-sizing: border-box; color: inherit; font-family:          Roboto Slab,Arial,sans-serif; font-size: 18px; font-weight: 500;          line-height: 1.1; margin-bottom: 40px; margin-top: 10px;\"><strong            style=\"box-sizing: border-box; font-weight: 700;\">Combination            Effects are Complex<\/strong><\/h4>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">A nitro-methanol fuel          mixture up to about 87-percent nitro, with increased richness,          is less prone to detonation. That is the same behavior as most          other fuels, especially alcohol fuels. However, a nitro-methanol          mixture above 87-percent nitro with increased richness becomes          more prone to detonation. That is because of an abundance of          excess oxygen in the fuel. That excess oxygen in the higher          percentage sensitizes the mixture towards lower auto-ignition          temperature. A richer mixture of high percentage nitro mixtures          has more excess oxygen and more detonation sensitivity.<\/p>\n<p style=\"box-sizing: border-box; line-height: 24px;          margin-bottom: 15px; margin-left: 0px; margin-right: 0px;          margin-top: 0px; padding-bottom: 0px; padding-left: 20px;          padding-right: 20px; padding-top: 0px;\">If there is one thing to          take away from all this, it\u2019s that in a racing environment, the          cause of detonation can be a complex issue, and isn\u2019t as simple          as \u201cIf X happens, then perform Y to fix.\u201d When you\u2019re at this          level of performance the number of factors that could be          affecting your power-robbing and potentially engine-damaging          detonation issue requires a thorough understanding of what is          happening with your fuel between the time it is first introduced          to the atmosphere and the opening of your exhaust valve.<\/p>\n<\/p><\/div>\n<\/p><\/div>\n","protected":false},"excerpt":{"rendered":"<p>By Jennifer Szabo June 20, 2019 In the engine tuning world, detonation is defined as one of the following: combustion [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center 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